Common names:
Valeric acid | Pentanoic acid |
Caproic acid | Hexanoic acid |
Malic acid | HOOC-CH(OH)-CH2-COOH | Phosgene | Cl-CO-Cl |
Urea/carbamide | NH2-CO-NH2 |
Carbamic acid | NH2-COOH |
Carbamoyl urea | NH2-CO-NH-CO-NH2 |
Ethyl carbamate | NH2-CO-CH2-CH3 |
Cyanamide | NH2-C≡N |
Urethane | CH3-NH-CO-O-CH2-CH3 |
IUPAC(prefix,suffix):
Group | prefix | suffix | |
---|---|---|---|
Alkenyne | (none) | -en-yne | |
Halide | Halo- | _ | |
Alcohol | Hydroxy- | -ol | |
Carboxylic acid | Carboxy- | -oic acid | |
Aldehyde | Formyl- | -al | |
Ketone | Oxo- | -one | |
Nitrile | Cyano- | -nitrile | |
Ethers | (small)oxy- | _ | |
Ester | Alkyl(OR')- | + | -oate(R+1) |
Acyl halide | Halo carbonyl- | -oyl halide | |
Amides | Carbamyl- | -amide(N-group1,group2) | |
Anhydride | _ | -oic anhydride(Roic R'oic) | |
Acid hydrazide{-CO-NHNH2} | _ | -ohydrazide | |
Acid azide{-CO-N3} | _ | -azide | |
Hydroxamic acids{-CO-NHOH} | _ | -ohydroxamic | |
Thioacids | Carbothioic acid- | -thioic acid | |
Thioester | Alkyl(SR')- | + | -thioate (R+1) |
Thiol | mercapto- | -thiol | |
Thioether | Smallylthio- | _ [or Ryl R'yl thio ether] | |
Amines(1°) | Amino- | -amine | |
Amines(2°&3°) | N-smallyl | + | -amine |
Nitro{-NO2} | Nitro | _ | |
Alkyl nitrite{-ONO} | _ | -nitrite | |
Isonitrile | [Ryl isocyanide or (R+1)yl isonitrile or Ryl carbyl amine] | ||
Sulphonic acids{-SO3H} | Sulpho- | -sulphonic acid | |
Imines | Alakanal- | + | -imine |
Cyclic ethers(Ring has n atoms) | 1,n-1-epoxy- | _ |
Special:
Lactones(cyclic esters)(n-member ring) (n-2)th greek letter-lactone
Lactam(cyclic amides)(n-member ring) (n-2)th greek letter-lactam
Cyclic compound nomenclature:
Alicyclic Cyclo-
Bicyclic bicyclo[m,n,o] (m+n+o+2)ane
[m=n(carbon,large ring)-2,n=n(carbon,small ring)-2,
o=n(carbon,b/w bridgeheads)]
Numbering from large ring to small ring
Tricyclic tricyclo[m,n,o,p] (m+n+o+p+2)ane
[m=n(carbon,large ring)-2,n=n(carbon,small ring)-2,
o=n(carbon,smallest ring-2),p=n(carbon,b/w bridgeheads)]
Numbering from large ring to small ring
Spiro spiro[m,n] (m+n+1)ane
[m=n(carbon,small ring)-1,n=n(carbon,large ring)-1]
Numbering from small ring to large ring
Special rule:
When 3 or more like functional groups are present in an unbranched carbon
chain then their carbons are not part of the name of the chain
Ex: HOOC-CH2-CH2-CH(COOH)-CH2-CH2-COOH is named Penta-1,3,5-trioic acid
Functional group priority order:
-COOH > -SO3H > -COOR > -COX > -CONH2 > -C≡N > -CHO > -CO- > -OH > -NH2 > --C=C-- > -C≡C-
Aromatic named substituents:
Substituent | Name |
---|---|
Ph- | Phenyl |
Ph-CH2- | Benzyl |
Ph-CH-- | Benzal |
Ph-C--- | Benzo |
Ph-CO- | Benzoyl |
C6H4-- | o/m/p - phenylene |
Ph-C≡N | Benzonitrile |
Ph-OH | Phenol |
Ph-CH3 | Toulene |
Ph-COOH | Benzanoic acid |
Ph-CHO | Benzaldehyde |
Ph-CO-CH3 | Acetophenone |
Ph-CO-Ph | Benzophenone |
Ph-CH=CH2 | Styrene |
Ph-O-CH3 | Anisole |
Ph-NH2 | Aniline |
Ph-SO3H | Benzene sulphonic acid |
Me-Toulene | o/m/p - xylene |
1,3,5 trimethyl benzene | Mesitylene |
Isopropyl benzene | Cumene |
Ph-O-CH2-CH3 | Phenetole |
Multi-ringed aromatic compounds:
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